| 5. Journée | 25.09.2005 | AS Livorno | - | Ascoli Calcio | 2:0 | ||||
| 8. Journée | 23.10.2005 | AS Livorno | - | Reggina Calcio | 1:0 | ||||
| 9. Journée | 26.10.2005 | Cagliari Calcio | - | AS Livorno | 1:1 |  |
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| 10. Journée | 30.10.2005 | AS Livorno | - | Parma FC | 2:0 | ||||
| 11. Journée | 06.11.2005 | Juventus | - | AS Livorno | 3:0 |  |
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| 15. Journée | 11.12.2005 | AS Livorno | - | Lazio Roma | 2:1 |
Italie