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| H (Match allé) | Tupi - MG | - | Internacional | 1:4 (0:2) | ||
| R (match retour) | Internacional | - | Tupi - MG | 5:0 (1:0) | ||
| H (Match allé): 05.05.2021 00:00 | R (match retour): 08.05.2021 00:00 | vainqueur: Internacional | ||||
| H (Match allé) | ABC - RN | - | Avai - SC | 0:3 (0:0) | ||
| R (match retour) | Avai - SC | - | ABC - RN | 0:3 (0:3) | ||
| H (Match allé): 05.05.2021 20:00 | R (match retour): 09.05.2021 11:00 | |||||
| H (Match allé) | Botafogo - RJ | - | São José - RS | 2:0 (1:0) | ||
| R (match retour) | São José - RS | - | Botafogo - RJ | 1:1 (1:1) | ||
| H (Match allé): 05.05.2021 20:00 | R (match retour): 09.05.2021 20:00 | vainqueur: Botafogo - RJ | ||||
| H (Match allé) | Coritiba - PR | - | Bahia - BA | 1:0 (1:0) | ||
| R (match retour) | Bahia - BA | - | Coritiba - PR | 2:2 (2:2) | ||
| H (Match allé): 05.05.2021 20:00 | R (match retour): 10.05.2021 20:00 | vainqueur: Coritiba - PR | ||||
| H (Match allé) | CEU - MS | - | Floresta - CE | 1:2 (0:1) | ||
| R (match retour) | Floresta - CE | - | CEU - MS | 5:0 (3:0) | ||
| H (Match allé): 05.05.2021 21:00 | R (match retour): 12.05.2021 14:30 | vainqueur: Floresta - CE | ||||
| H (Match allé) | São Raimundo - RR | - | Vasco da Gama | 1:3 (0:3) | ||
| R (match retour) | Vasco da Gama | - | São Raimundo - RR | 4:2 (2:0) | ||
| H (Match allé): 05.05.2021 22:00 | R (match retour): 09.05.2021 20:00 | vainqueur: Vasco da Gama | ||||
| H (Match allé) | Atlético Mineiro | - | Galvez - AC | 5:0 (1:0) | ||
| R (match retour) | Galvez - AC | - | Atlético Mineiro | 2:2 (0:2) | ||
| H (Match allé): 05.05.2021 22:00 | R (match retour): 10.05.2021 00:00 | vainqueur: Atlético Mineiro | ||||
| H (Match allé) | Palmeiras | - | Náutico - PE | 4:0 (3:0) | ||
| R (match retour) | Náutico - PE | - | Palmeiras | 1:2 (1:2) | ||
| H (Match allé): 06.05.2021 01:00 | R (match retour): 09.05.2021 21:00 | vainqueur: Palmeiras | ||||
