| 4. Journée | 20.08.2022 | Cove Rangers | - | Ayr United | 1:2 | ||||
| 8. Journée | 17.09.2022 | Raith Rovers | - | Ayr United | 3:2 | ||||
| 10. Journée | 08.10.2022 | Ayr United | - | Queen's Park FC | 5:0 | ||||
| 18. Journée | 17.12.2022 | Partick Thistle | - | Ayr United | 3:2 | ||||
| 19. Journée | 23.12.2022 | Ayr United | - | Dundee FC | 0:2 |  |
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| 23. Journée | 27.01.2023 | Cove Rangers | - | Ayr United | 0:5 |
RD Congo