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| 17.10.1965 | Sporting Gijón | - | SD Indautxu | 1:1 | ||
| RC Celta | - | CA Osasuna | 3:1 | |||
| Deportivo La Coruña | - | Real Oviedo | 0:0 | |||
| UP Langreo | - | Barakaldo CF | 3:2 | |||
| CE Europa | - | Burgos CF | 3:1 | |||
| CF Badalona | - | CE L'Hospitalet | 1:0 | |||
| CD Condal | - | Racing Santander | 4:1 | |||
| Real Sociedad | - | UE Lleida | 2:1 | |||
| CD Badajoz | - | UD Melilla | 3:1 | |||
| Cádiz CF | - | CD Tenerife | 1:3 | |||
| Hércules CF | - | CD Mestalla | 0:0 | |||
| Real Murcia | - | Real Valladolid | 0:2 | |||
| Rayo Vallecano | - | Algeciras CF | 1:0 | |||
| Levante UD | - | Granada CF | 2:0 | |||
| CF Calvo Sotelo | - | Recreativo Huelva | 1:0 | |||
| CA Ceuta | - | CD Constància | 3:0 |
| » Classement | équipe recevante | à l'extérieur | Premier tour | Second tour |
| 1 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Sporting Gijón | 7 | 5 | 1 | 1 | 16:9 | 7 | 11:3 |
| 2 |
|
Deportivo La Coruña | 7 | 5 | 1 | 1 | 12:5 | 7 | 11:3 |
| 3 |
|
RC Celta | 7 | 5 | 0 | 2 | 14:8 | 6 | 10:4 |
| 4 |
|
Real Oviedo | 7 | 4 | 1 | 2 | 15:6 | 9 | 9:5 |
| 5 |
|
CF Badalona | 7 | 4 | 1 | 2 | 7:7 | 0 | 9:5 |
| 6 |
|
Real Sociedad | 7 | 4 | 1 | 2 | 13:11 | 2 | 9:5 |
| 7 |
|
Burgos CF | 7 | 3 | 1 | 3 | 10:11 | -1 | 7:7 |
| 8 |
|
SD Indautxu | 7 | 3 | 1 | 3 | 11:12 | -1 | 7:7 |
| 9 |
|
CD Condal | 7 | 3 | 1 | 3 | 13:13 | 0 | 7:7 |
| 10 |
|
Racing Santander | 7 | 3 | 0 | 4 | 9:11 | -2 | 6:8 |
| 11 |
|
CE Europa | 7 | 3 | 0 | 4 | 10:12 | -2 | 6:8 |
| 12 |
|
UE Lleida | 7 | 2 | 1 | 4 | 8:8 | 0 | 5:9 |
| 13 |
|
CA Osasuna | 7 | 2 | 1 | 4 | 6:10 | -4 | 5:9 |
| 14 |
|
CE L'Hospitalet | 7 | 2 | 0 | 5 | 7:14 | -7 | 4:10 |
| 15 |
|
UP Langreo | 7 | 2 | 0 | 5 | 8:13 | -5 | 4:10 |
| 16 |
|
Barakaldo CF | 7 | 1 | 0 | 6 | 5:14 | -9 | 2:12 |
| 2 | |||||||||
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Granada CF | 7 | 6 | 0 | 1 | 12:4 | 8 | 12:2 |
| 2 |
|
Levante UD | 7 | 4 | 2 | 1 | 14:4 | 10 | 10:4 |
| 3 |
|
CD Mestalla | 7 | 3 | 3 | 1 | 11:6 | 5 | 9:5 |
| 4 |
|
CF Calvo Sotelo | 7 | 4 | 1 | 2 | 10:7 | 3 | 9:5 |
| 5 |
|
Hércules CF | 7 | 3 | 2 | 2 | 8:5 | 3 | 8:6 |
|
Rayo Vallecano | 7 | 3 | 2 | 2 | 8:5 | 3 | 8:6 | |
| 7 |
|
CA Ceuta | 7 | 3 | 2 | 2 | 9:10 | -1 | 8:6 |
| 8 |
|
CD Tenerife | 7 | 4 | 0 | 3 | 15:5 | 10 | 8:6 |
| 9 |
|
CD Constància | 7 | 3 | 1 | 3 | 5:13 | -8 | 7:7 |
| 10 |
|
Real Valladolid | 7 | 2 | 3 | 2 | 8:10 | -2 | 7:7 |
| 11 |
|
Cádiz CF | 7 | 2 | 2 | 3 | 7:8 | -1 | 6:8 |
| 12 |
|
CD Badajoz | 7 | 2 | 1 | 4 | 5:13 | -8 | 5:9 |
| 13 |
|
Algeciras CF | 7 | 2 | 0 | 5 | 5:6 | -1 | 4:10 |
| 14 |
|
Real Murcia | 7 | 2 | 0 | 5 | 4:9 | -5 | 4:10 |
| 15 |
|
Recreativo Huelva | 7 | 2 | 0 | 5 | 5:8 | -3 | 4:10 |
| 16 |
|
UD Melilla | 7 | 1 | 1 | 5 | 6:19 | -13 | 3:11 |
