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| 30.09.2022 | 21:00 | Athletic Bilbao | - | UD Almería | 4:0 (2:0) | |
| 01.10.2022 | 14:00 | Cádiz CF | - | Villarreal CF | 0:0 (0:0) | |
| 16:15 | Getafe CF | - | Real Valladolid | 2:3 (2:2) | ||
| 18:30 | Sevilla FC | - | Atlético Madrid | 0:2 (0:1) | ||
| 21:00 | RCD Mallorca | - | FC Barcelona | 0:1 (0:1) | ||
| 02.10.2022 | 14:00 | Espanyol Barcelona | - | Valencia CF | 2:2 (0:0) | |
| 16:15 | RC Celta | - | Real Betis | 1:0 (1:0) | ||
| 18:30 | Girona FC | - | Real Sociedad | 3:5 (2:2) | ||
| 21:00 | Real Madrid | - | CA Osasuna | 1:1 (1:0) | ||
| 03.10.2022 | 21:00 | Rayo Vallecano | - | Elche CF | 2:1 (1:1) |
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
FC Barcelona | 7 | 6 | 1 | 0 | 19:1 | 18 | 19 |
| 2 |
|
Real Madrid | 7 | 6 | 1 | 0 | 18:7 | 11 | 19 |
| 3 |
|
Athletic Bilbao | 7 | 5 | 1 | 1 | 16:4 | 12 | 16 |
| 4 |
|
Real Betis | 7 | 5 | 0 | 2 | 10:5 | 5 | 15 |
| 5 |
|
Atlético Madrid | 7 | 4 | 1 | 2 | 12:6 | 6 | 13 |
| 6 |
|
Real Sociedad | 7 | 4 | 1 | 2 | 12:11 | 1 | 13 |
| 7 |
|
CA Osasuna | 7 | 4 | 1 | 2 | 8:6 | 2 | 13 |
| 8 |
|
Villarreal CF | 7 | 3 | 3 | 1 | 10:2 | 8 | 12 |
| 9 |
|
Rayo Vallecano | 7 | 3 | 1 | 3 | 9:9 | 0 | 10 |
| 10 |
|
Valencia CF | 7 | 3 | 1 | 3 | 12:7 | 5 | 10 |
| 11 |
|
RC Celta | 7 | 3 | 1 | 3 | 9:13 | -4 | 10 |
| 12 |
|
RCD Mallorca | 7 | 2 | 2 | 3 | 6:8 | -2 | 8 |
| 13 |
|
Real Valladolid | 7 | 2 | 1 | 4 | 6:13 | -7 | 7 |
| 14 |
|
Girona FC | 7 | 2 | 1 | 4 | 10:12 | -2 | 7 |
| 15 |
|
Getafe CF | 7 | 2 | 1 | 4 | 8:15 | -7 | 7 |
| 16 |
|
Espanyol Barcelona | 7 | 1 | 2 | 4 | 9:14 | -5 | 5 |
| 17 |
|
Sevilla FC | 7 | 1 | 2 | 4 | 7:13 | -6 | 5 |
| 18 |
|
Cádiz CF | 7 | 1 | 1 | 5 | 1:14 | -13 | 4 |
| 19 |
|
UD Almería | 7 | 1 | 1 | 5 | 4:11 | -7 | 4 |
| 20 |
|
Elche CF | 7 | 0 | 1 | 6 | 3:18 | -15 | 1 |
| Champions League | |
| Europa League | |
| Relégation |
