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| 01.10.2021 | 21:00 | Athletic Bilbao | - | CD Alavés | 1:0 (1:0) | |
| 02.10.2021 | 14:00 | CA Osasuna | - | Rayo Vallecano | 1:0 (0:0) | |
| 16:15 | RCD Mallorca | - | Levante UD | 1:0 (0:0) | ||
| 18:30 | Cádiz CF | - | Valencia CF | 0:0 (0:0) | ||
| 21:00 | Atlético Madrid | - | FC Barcelona | 2:0 (2:0) | ||
| 03.10.2021 | 14:00 | Elche CF | - | RC Celta | 1:0 (0:0) | |
| 16:15 | Espanyol Barcelona | - | Real Madrid | 2:1 (1:0) | ||
| 18:30 | Getafe CF | - | Real Sociedad | 1:1 (1:0) | ||
| 18:30 | Villarreal CF | - | Real Betis | 2:0 (1:0) | ||
| 21:00 | Granada CF | - | Sevilla FC | 1:0 (1:0) |
| # | Équipe | M. | G. | N. | P. | Buts | Diff. | Pts. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Real Madrid | 8 | 5 | 2 | 1 | 22:10 | 12 | 17 |
| 2 |
|
Atlético Madrid | 8 | 5 | 2 | 1 | 11:6 | 5 | 17 |
| 3 |
|
Real Sociedad | 8 | 5 | 2 | 1 | 11:7 | 4 | 17 |
| 4 |
|
Sevilla FC | 8 | 4 | 3 | 1 | 11:4 | 7 | 15 |
| 5 |
|
CA Osasuna | 8 | 4 | 2 | 2 | 11:11 | 0 | 14 |
| 6 |
|
Villarreal CF | 8 | 3 | 5 | 0 | 13:5 | 8 | 14 |
| 7 |
|
Rayo Vallecano | 8 | 4 | 1 | 3 | 13:8 | 5 | 13 |
| 8 |
|
FC Barcelona | 8 | 3 | 4 | 1 | 12:8 | 4 | 13 |
| 9 |
|
Athletic Bilbao | 8 | 3 | 4 | 1 | 7:4 | 3 | 13 |
| 10 |
|
Valencia CF | 8 | 3 | 3 | 2 | 12:8 | 4 | 12 |
| 11 |
|
Real Betis | 8 | 3 | 3 | 2 | 11:9 | 2 | 12 |
| 12 |
|
RCD Mallorca | 8 | 3 | 2 | 3 | 7:12 | -5 | 11 |
| 13 |
|
Elche CF | 8 | 2 | 3 | 3 | 5:8 | -3 | 9 |
| 14 |
|
Espanyol Barcelona | 8 | 2 | 3 | 3 | 6:8 | -2 | 9 |
| 15 |
|
RC Celta | 8 | 2 | 1 | 5 | 7:11 | -4 | 7 |
| 16 |
|
Cádiz CF | 8 | 1 | 4 | 3 | 7:11 | -4 | 7 |
| 17 |
|
Granada CF | 8 | 1 | 3 | 4 | 6:12 | -6 | 6 |
| 18 |
|
Levante UD | 8 | 0 | 4 | 4 | 6:13 | -7 | 4 |
| 19 |
|
CD Alavés | 8 | 1 | 0 | 7 | 4:17 | -13 | 3 |
| 20 |
|
Getafe CF | 8 | 0 | 1 | 7 | 3:13 | -10 | 1 |
| Champions League | |
| Europa League | |
| Relégation |
