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| H (Match allé) | Flamengo RJ | - | Palmeiras | 7:3 (4:0) | ||
| R (match retour) | Palmeiras | - | Flamengo RJ | 3:5 (2:3) | ||
| H (Match allé): 05.10.2021 20:15 | R (match retour): 13.10.2021 22:00 | vainqueur: Flamengo RJ | ||||
| H (Match allé) | Atlético Mineiro | - | São Paulo FC | 0:1 (0:1) | ||
| R (match retour) | São Paulo FC | - | Atlético Mineiro | 3:1 (2:1) | ||
| H (Match allé): 07.10.2021 21:00 | R (match retour): 19.10.2021 21:00 | vainqueur: São Paulo FC | ||||
