| 2. Journée | 05.08.2022 | Queen's Park FC | - | Ayr United | 2:3 | ||||
| 3. Journée | 13.08.2022 | Ayr United | - | Hamilton Academical | 2:2 | ||||
| 4. Journée | 20.08.2022 | Cove Rangers | - | Ayr United | 1:2 | ||||
| 5. Journée | 26.08.2022 | Ayr United | - | Dundee FC | 3:1 |  |
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| 6. Journée | 03.09.2022 | Greenock Morton FC | - | Ayr United | 1:2 |  |
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| 8. Journée | 17.09.2022 | Raith Rovers | - | Ayr United | 3:2 | ||||
| 9. Journée | 01.10.2022 | Ayr United | - | Inverness CT | 0:1 | ||||
| 10. Journée | 08.10.2022 | Ayr United | - | Queen's Park FC | 5:0 | ||||
| 11. Journée | 15.10.2022 | Dundee FC | - | Ayr United | 2:1 | ||||
| 12. Journée | 22.10.2022 | Ayr United | - | Cove Rangers | 2:2 | ||||
| 7. Journée | 25.10.2022 | Ayr United | - | Partick Thistle | 4:2 | ||||
| 13. Journée | 29.10.2022 | Arbroath FC | - | Ayr United | 0:2 | ||||
| 23. Journée | 27.01.2023 | Cove Rangers | - | Ayr United | 0:5 | ||||
| 24. Journée | 03.02.2023 | Queen's Park FC | - | Ayr United | 2:0 | ||||
| 20. Journée | 07.03.2023 | Greenock Morton FC | - | Ayr United | 1:3 | |
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| 33. Journée | 15.04.2023 | Partick Thistle | - | Ayr United | 1:1 | ||||
| 34. Journée | 21.04.2023 | Ayr United | - | Queen's Park FC | 0:0 |
Écosse